PBAT (short for polybutylene adipate terephthalate) is a biodegradable random copolymer, specifically a copolyester of adipic acid, 1,4-butanediol and terephthalic acid. PBAT is produced by many different manufacturers and may be known by the brand names ecoflex, Wango, Ecoworld, Eastar Bio, and Origo-Bi. It is also called poly(butylene adipate-co-terephthalate) and sometimes polybutyrate-adipate-terephthalate[1] (a misnomer) or even just "polybutyrate".[2] It is generally marketed as a fully biodegradable alternative to low-density polyethylene, having many similar properties including flexibility and resilience, allowing it to be used for many similar uses such as plastic bags and wraps.[3] The structure is a random-block polymer consisting of butanediol–adipic acid and butanediol-terephthalic acid blocks.
PBAT is classified as a random copolymer due to its random structure. This also means that it cannot crystallize to any significant degree due to the absence of any kind of structural order. This leads to several physical properties: wide melting point, low elastic modulus and stiffness, but high flexibility and toughness. The flexibility and toughness of this polymer makes it ideal for blending with another biodegradable polymer that is strong and rigid for bottle production.[5]
The drawback of this polymer is that if it has high flexibility and toughness, then it will not be strong and rigid. This makes it non-ideal for any situation in which a strong, rigid container is desired. An example of this would be transparent barriers, such as those made of plexiglass (Poly(methyl methacrylate)), a transparent glass substitute.[5]
PBAT is fully biodegradable when composted due to the presence of butylene adipate groups. The high stability and mechanical properties come from the terephthalate portions.[5]
Does not degrade in marine and fresh water.[7]
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